Environmental Health & Safety

Safety Instruction 30

Chemical Storage Guidelines

Update 09/04/2007

Proper chemical storage is essential in assuring a safe work environment 

Segregate Chemicals - Store By Hazard Class

Do Not Store Chemicals Alphabetically, except within a hazard class. Hazard classes that should be stored separately include: 

Provide physical segregation (sills, curbs, trays) or separation between hazard classes. 

Keep flammable materials by themselves in approved storage cans, cabinets, or rooms. Store oxidizers well away from flammable materials. 

Store Chemicals To Minimize The Risk From Damaged Containers

Label Chemical Containers And Storage Areas Properly

Chemical Hazard Classes - Examples

Pyrophoric - (many are also water reactive)

  • phosphorous (red, white)
  • methylmagnesium bromide (and other grignard reagents
  • diethylzinc
  • triethylaluminum

Oxidizing Materials

  • nitrates
  • perchlorates
  • permanganates
  • iodates
  • chromium (VI) compounds
  • bromine
  • nitrates
  • iodine

Water Reactive

  • alkaline earth metals (sodium, potassium, lithium, calcium)
  • calcium carbide
  • hydrides
  • titanium tetrachloride
  • acetic anhydride

Flammable

  • solvents
  • sodium metal
  • sodium sulfide
  • sulfur

Inorganic Acids

  • hydrochloric acid
  • hydroiodic acid
  • phosphoric acid
  • hydrobromic acid
  • hydrofluoric acid

Inorganic Acids - Oxidizing

  • sulfuric acid
  • nitric acid
  • perchloric acid

Organic Acids

  • formic acid
  • acetic acid
  • propionic acid
  • butyric acid

Caustics

  • hydroxides of sodium, potassium, calcium, lithium