| Safety Instruction 30 |
Chemical Storage
Guidelines
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Update 09/04/2007 |
Proper chemical storage is essential in assuring a safe
work environment
Segregate Chemicals - Store By Hazard Class
Do Not Store Chemicals Alphabetically, except
within a hazard class. Hazard classes that should be stored separately include:
- radioactive materials
- pyrophoric materials
- flammable materials
- oxidizing materials
- water reactive substances
- oxidizing acids
- inorganic acids
- organic acids
- caustics (bases)
- poisons (general laboratory reagents separated into organic
and inorganic groups)
Provide physical segregation (sills, curbs, trays) or separation between hazard classes.
Keep flammable materials by themselves in
approved storage cans, cabinets, or rooms. Store oxidizers well away from flammable
materials.
Store Chemicals To Minimize The Risk From Damaged Containers
- Store large bottles
and containers close to but not on the floor
- Store acids and caustics below eye level
- Shelves should
be securely fastened to the wall and have lips or restraining cord
to prevent bottles from falling
- Secondary containment such as polyethylene or stainless steel trays as appropriate should be provided
for spill protection
Label Chemical Containers And Storage Areas Properly
- Chemical containers should have the chemical name, a warning label identifying the major hazards,
and information about handling precautions
- Storage areas should be labeled with hazard class
Chemical Hazard Classes - Examples
Pyrophoric - (many are also water reactive)
- phosphorous (red, white)
- methylmagnesium bromide (and other grignard reagents
- diethylzinc
- triethylaluminum
Oxidizing Materials
- nitrates
- perchlorates
- permanganates
- iodates
- chromium (VI) compounds
- bromine
- nitrates
- iodine
Water Reactive
- alkaline earth metals (sodium, potassium, lithium,
calcium)
- calcium carbide
- hydrides
- titanium tetrachloride
- acetic anhydride
Flammable
- solvents
- sodium metal
- sodium sulfide
- sulfur
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Inorganic Acids
- hydrochloric acid
- hydroiodic acid
- phosphoric acid
- hydrobromic acid
- hydrofluoric acid
Inorganic Acids - Oxidizing
- sulfuric acid
- nitric acid
- perchloric acid
Organic Acids
- formic acid
- acetic acid
- propionic acid
- butyric acid
Caustics
- hydroxides of sodium, potassium, calcium, lithium
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